Previously, the analysis of energy demand for wastewater treatment was often limited to one-dimensional analyses of electricity demand. How ever, a comprehensive analysis requires the inclusion of all different contributions to energy demand. The Life Cycle Assessment (LCA) methodology defined in ISO 14040/44 is a suitable tool for this task. With it, all different primary and secondary energy demands can be quantified and assessed using consistent indicators, complemented by an assessment of other environmental impacts such as the carbon footprint.

The Water supply and sanitation Technology Platform (WssTP) was initiated by the European Commission in 2004. It is led by industries in collaboration with academics, research organisations and water users to help structure the European Research Area and identify R&D needs for the water sector. In December 2008, the board of the WssTP identified the need to create a Task Force on Climate Change in order to build a working group focused on the issue and able to assist the EU Commission in the related Calls for Projects. The Task Force on Climate Change did a review on the research and technology development (RTD) needs related to each of the WssTP topics, highlighting the challenges they will face in a climate change context. This paper is based on the review carried out and presents its main conclusions. The RTD topics identified involve a broad range of expertise areas and can be divided into two main groups: mitigation and adaptation. The latter will be brought to the fore in this paper.

The oxygen-consuming processes in the hypolimnia of freshwater lakes leading to deep-water anoxia are still not well understood, thereby constraining suitable management concepts. This study presents data obtained from 11 eutrophic lakes and suggests a model describing the consumption of dissolved oxygen (O2) in the hypolimnia of eutrophic lakes as a result of only two fundamental processes: O2 is consumed (i) by settled organic material at the sediment surface and (ii) by reduced substances diffusing from the sediment. Apart from a lake’s productivity, its benthic O2 consumption depends on the O2 concentration in the water overlying the sediment and the molecular O2 diffusion to the sediment. On the basis of observational evidence of long-term monitoring data from 11 eutrophic lakes, we found that the areal hypolimnetic mineralization rate ranging from 0.47 to 1.31 g ofO2 m-2 d-1 (average 0.90 ± 0.30) is a function of (i) a benthic flux of reduced substances (0.37 ± 0.12 g ofO2 m-2 d-1) and (ii) an O2 consumption which linearly increases with the mean hypolimnion thickness (zH)upto ~25 m. This model has important implications for predicting and interpreting the response of lakes and reservoirs to restoration measures.

Managed aquifer recharge (MAR) provides efficient removal for many organic compounds and sum parameters. However, observed in situ removal efficiencies tend to scatter and cannot be predicted easily. In this paper, a method is introduced which allows to identify and eliminate biased samples and to quantify simultaneously the impact of (i) redox conditions (ii) kinetics (iii) residual threshold values below which no removal occurs and (iv) field site specifics. It enables to rule out spurious correlations between these factors and therefore improves the predictive power. The method is applied to an extensive database from three MAR field sites which was compiled in the NASRI project (2002e2005, Berlin, Germany). Removal characteristics for 38 organic parameters are obtained, of which 9 are analysed independently in 2 different laboratories. Out of these parameters, mainly pharmaceutically active compounds (PhAC) but also sum parameters and industrial chemicals, four compounds are shown to be readily removable whereas six are persistent. All partly removable compounds show a redox dependency and most of them reveal either kinetic dependencies or residual threshold values, which are determined. Differing removal efficiencies at different field sites can usually be explained by characteristics (i) to (iii).

The herbicide Glyphosate was detected in River Havel (Berlin, Germany) in concentrations between 0.1 and 2 µg/L (single maximum outlier: 5 µg/L). As the river indirectly acts as drinking water source for the city's 3.4 Mio inhabitants potential risks for drinking water production needed to be assessed. For this reason laboratory (sorption and degradation studies) and technical scale investigations (bank filtration and slow sand filter experiments) were carried out. Batch adsorption experiments with Glyphosate yielded a low KF of 1.89 (1/n = 0.48) for concentrations between 0.1 and 100 mg/L. Degradation experiments at 8 °C with oxygen limitation resulted in a decrease of Glyphosate concentrations in the liquid phase probably due to slow adsorption (half life: 30 days).During technical scale slow sand filter (SSF) experiments Glyphosate attenuation was 70-80% for constant inlet concentrations of 0.7, 3.5 and 11.6 µg/L, respectively. Relevant retardation of Glyphosate breakthrough was observed despite the low adsorption potential of the sandy filter substrate and the relatively high flow velocity. The VisualCXTFit model was applied with data from typical Berlin bank filtration sites to extrapolate the results to a realistic field setting and yielded sufficient attenuation within a few days of travel time. Experiments on an SSF planted with Phragmites australis and an unplanted SSF with mainly vertical flow conditions to which Glyphosate was continuously dosed showed that in the planted SSF Glyphosate retardation exceeds 54% compared to 14% retardation in the unplanted SSF. The results show that saturated subsurface passage has the potential to efficiently attenuate glyphosate, favorably with aerobic conditions, long travel times and the presence of planted riparian boundary buffer strips.

GaN-based ultraviolet-C (UVeC) light emitting diodes (LEDs) are of great interest for water disinfection. They offer significant advantages compared to conventional mercury lamps due to their compact form factor, low power requirements, high efficiency, non-toxicity, and overall robustness. However, despite the significant progress in the performance of semiconductor based UV LEDs that has been achieved in recent years, these devices still suffer from low emission power and relatively short lifetimes. Even the best UV LEDs exhibit external quantum efficiencies of only 1e2%. The objective of this study was to investigate the suitability of GaN-based UV LEDs for water disinfection. The investigation included the evaluation of the performance characteristics of UV LEDs at different operating conditions as well as the design of a UV LED module in view of the requirements for water treatment applications. Bioanalytical testing was conducted using Bacillus subtilis spores as test organism and UV LED modules with emission wavelengths of 269 nm and 282 nm. The results demonstrate the functionality of the developed UV LED disinfection modules. GaN-based UV LEDs effectively inactivated B. subtilis spores during static and flow-through tests applying varying water qualities. The 269 nm LEDs reached a higher level of inactivation than the 282 nm LEDs for the same applied fluence. The lower inactivation achieved by the 282 nm LEDs was compensated by their higher photon flux. First flow-through tests indicate a linear correlation between inactivation and fluence, demonstrating a well designed flow-through reactor. With improved light output and reduced costs, GaN-based UV LEDs can provide a promising alternative for decentralised and mobile water disinfection systems.

It was the aim of the EU funded research project TECHNEAU to investigate the relevance and feasibility of bank filtration (BF) plus post-treatment for newly industrialised and developing countries. Field studies at BF sites in Delhi (India) were supplemented by literature studies and modelling in order to investigate if this natural drinking water (pre-) treatment is a sustainable option to provide safe drinking water for countries like India. The results showed that especially for those substances that are of relevance in newly industrialised and developing countries subsurface passage can represent an efficient barrier. However, certain limiting factors for BF application also need to be considered: high ammonium levels in surface water, usually associated with high shares of poorly or un-treated sewage, will not be mitigated during subsurface passage and require extensive post-treatment. In order to support decision makers in the difficult task of assessing the feasibility of BF systems at a certain site a simple decision support system was developed. This simple tool enables to assess a range of abstraction rates and well locations for a specific field site that could fit with their needs (e.g. minimum required travel time or share of BF).

The occurrence of the cyanobacterial toxins anatoxin-a (ATX) and cylindrospermopsin (CYN) in surface waters has been reported throughout the world. Beside degradation, sorption is an important pathway for toxin elimination if these resources are used for drinking water production via sediment passage. However, to date studies that systematically investigated sorption of these toxins onto sediments are lacking. Therefore, the aim of our work was (i) to determine the adsorption coefficients of ATX and CYN according to the Freundlich and Langmuir model for sediments of various textures and (ii) to derive sorptionrelevant sediment characteristics. We determined sorption parameters in air-dried samples of eight differently textured sediments using batch experiments. Results for both toxins showed best fits with the Langmuir model. Organic C proved to be the main sediment parameter determining CYN sorption. There was no or little CYN sorption on sandy and silty sediments (0e39 mg kg-1), respectively, presumably due to charge repulsion from the negatively charged surfaces. Sorption of ATX (max. sorbent loading ranging from 47 to 656 mg kg-1) was much stronger than that of CYN (max. sorbent loading ranging from 0 to 361 mg kg-1) and predominantly controlled by clay and to a minor degree also by organic C and silt. While ATX sorption to most sediments occurred mainly through cation exchange this mechanism played only a minor role in CYN sorption to organic C. Hence, high mobility for CYN and moderate mobility for ATX during sediment passage has to be expected.