Urban water infrastructures are increasingly facing challenges resulting from climate change and demographic developments. Using Berlin as an example, the project KURAS, which is supported by the Federal German Ministry for Education and Research, aims at demonstrating how the future waste water disposal, water quality, urban climate and quality of life in the city can be improved through intelligently coupled storm water and waste water management. The project consists of a network of partners from research and industry as well as Berlin decision makers (eight research institutions, four industrial partners, two public authorities and one public utility, responsible for drinking water supply and wastewater disposal).

Unbehandeltes Abwasser ist ein wertvoller Energieträger. Die hier enthaltenen organischen Stoffe haben so viel chemische Energie, dass sich damit die bisher in der Abwasserbehandlung benötigte Energiemenge komplett kompensieren und sogar noch ein Energieübersch uss erzeugen ließe. Wissenschaftler vom Kompetenzzentrum Wasser Berlin (KWB) haben einen neuen Prozess der Abwasserbehandlung entwickelt und im Pilotmaßstab getestet, um das erhebliche Energiepotenzial im Abwasser besser auszuschöpfen. Das Forschungsprojekt CARISMO ("CARbon IS MOney") hat eine Expertenjury für den Deutschen Nachhaltigkeitspreis nominiert.

Das Projekt soll mögliche Entlastungseffekte für die Berliner Gewässer durch Einsatz geeigneter Maßnahmen zur Reinigung von Straßenabläufen aufzeigen.

The present study aims to explore the relationship between rainfall variables and water quality/quantity characteristics of combined sewer overflows (CSO), by the use of multivariate statistical methods and online measurements at a principal CSO outlet in Berlin (Germany). Canonical correlation results showed that the maximum and average rainfall intensities are the most influential variables to describe CSO water quantity and pollutant loads whereas the duration of the rainfall event and the rain depth seem to be the most influential variables to describe CSO pollutant concentrations. The analysis of Partial Least Squares (PLS) regression models confirms the findings of the canonical correlation and highlights three main influences of rainfall on CSO characteristics: (i) CSO water quantity characteristics are mainly influenced by the maximal rainfall intensities, (ii) CSO pollutants concentrations were found to be mostly associated with duration of the rainfall and (iii) pollutants loads seemed to be principally influenced by dry weather duration before the rainfall event. The prediction quality of PLS models is rather low (R² < 0.6) but results can be useful to explore qualitatively the influence of rainfall on CSO characteristics.

The presented work studies the influence of the sampling strategy on the quality of locally calibrated UV-VIS probe measurements in combined sewer overflows (CSO) and the receiving river. Results indicate that UV-VIS spectrometers are not able to provide reliable measurements of water quality in urban stormwater without being calibrated to local conditions with laboratory analyses of water samples. The use of the global calibration (supplied by the manufacturer) led to errors of at least 30% and 45% for CSO load and river concentration of chemical oxygen demand (COD), respectively. Even with reliable local calibration, COD loads contained significant uncertainties close to 20%. Uncertainties in COD load and concentration decrease below 30% if more than 15-20 samples (i.e. 3-4 stormwater events) are sampled for local calibration. The effort and associated sampling costs to gain more than 15-20 samples are much less effective, since load and concentration uncertainties remain relatively stable with an increasing number of samples used for the calibration. The presented analysis aims at supporting practitioners in the planning, operation and calibration of UV-VIS spectrometer probes.

Purpose: The transport behavior of human pharmaceuticals in groundwater depends on a multitude of factors such as the physico-chemical conditions in the aquifer and the organic carbon content of the sediment, and, in particular, on the redox conditions in the groundwater. This is of special interest at managed aquifer recharge sites where the occurrence of trace organics is important for drinking water production. The aim of this study was to evaluate the possibility of influencing the redox system of the aquifer in a way that optimizes the potential of managed aquifer recharge systems to reduce the amount of trace organics. Materials and methods: Column studies were performed using natural and thermally treated sediments from an infiltration basin of the Berlin area, Germany. Special emphasis was placed on thermal treatment of the sediments to influence the total organic carbon (TOC) content in the sediment. In one experiment, the sediment was thermally pretreated at 550 °C, in two experiments the sediment was pretreated at 200 °C, and in one the sediment was untreated. Furthermore, the influence of ozonation, a very common disinfectant used in drinking water production, was studied in the experiments. The retardation and degradation parameters for primidone (PMD), carbamazepine (CBZ), and sulfamethoxazole (SMX) under different redox conditions were evaluated. Results and discussion: Oxic conditions were obtained in the experiment with low TOC (0. 06 wt%) in the sediment pre-treated at 550 °C. Anoxic conditions were predominant in two column experiments with a TOC content of 0. 17 wt% in the sediment, irrespective of the mode of treatment (natural or 200 °C). All three pharmaceutical compounds show almost conservative transport behavior with retardation factors between 1. 02 and 1. 25 for PMD, between 1. 06 and 1. 37 for CBZ, and between 1. 00 and 1. 08 for SMX. Differences in the transport behavior were observed depending on the TOC content of the sediment. For CBZ, and to a minor extent for PMD, the higher retardation factors were observed in the sediment with a TOC content of 0. 17 wt% under anoxic conditions. The ozonation of the influent water affects the influent concentrations of PMD, CBZ and SMX. However, it has no influence on the oxygen concentration of the column outflow. Conclusions: CBZ and PMD are retarded in the presence of organic matter in the aquifer. Variations of the TOC content of the sediment have a direct influence on the retardation of CBZ and PMD. The three human pharmaceuticals may be ranked in order of decreasing retardation: CBZ & PMD & SMX. The microbial activity in the experiments was not studied, although it can be assumed that the thermal pretreatment influences the microbial activity in the sediments. In particular, the microbial activity was severely inhibited at 550 °C, resulting in a shift of the redox conditions.

Municipal solid waste (MSW) in landfill bioreactors is subjected to mechanical, biological, and hydrological processes. To understand these processes, four large-scale bioreactor pilots were specifically designed to simulate the behavior of waste in the core of a landfill. Here, the results of two long-term tests that were performed in two compression cells are presented. Mechanical, biochemical, and hydrological parameters were analyzed throughout the experiments. The promising results of this research improve the understanding of biodegradation and its correlation with the hydromechanical behavior of municipal solid waste. In particular, the sensitivity of the biodegradation to leachate injection and the correlation between the biogas flow and vertical settlement were confirmed for wastes with high initial moisture content. The results showed that it is important to consider the potential of different monitoring techniques and the representative volume for the experimental approach. Furthermore, the operational results led to interesting conclusions, especially regarding the addition of moisture to waste, which is a key element for bioreactor landfill operation.

The present laboratory study tests the hypothesis that straw-bark mulch bioreactors are capable of concurrently retaining nitrate (NO3-) and the herbicides atrazine or bentazone at short hydraulic residence times (HRT). In a 1 year column experiment at HRT of ~4h three organic carbon sources, straw of common wheat (Triticum aestivum L.), bark mulch of pine tree (Pinus sp.) and a mixture of both materials, showed high reduction of continuously dosed NO3- (100mgL-1) with average denitrification rates of 23.4g-Nd-1m-3, 8.4g-Nd-1m-3 and 20.5g-Nd-1m-3, respectively. Under denitrifying conditions, fast and substantial retention of continuously dosed atrazine (20µgL-1) was observed with estimated dissipation times (DT50) between 0.12 and 0.49 days in the straw-bark mulch bioreactor. In parallel batch experiments, it could be confirmed that atrazine retention is based on adsorption to bark mulch and on degradation processes supplied by the organic materials as continual sources of carbon. In contrast, bentazone was not significantly reduced under the experimental conditions. While aging of materials was clearly observed in a reduction of denitrification by 60-70% during the experiment, systems still worked very well until the end of the experiment. The results indicate that the combined use of straw and bark mulch could increase the efficiency of mitigation systems, which are installed to improve the quality of drainage water before its release to surface waters. Further, the addition of these materials has the potential of parallel retention of NO3- and less mobile herbicides like atrazine, even during high flow events, as expected at the outlet of agricultural drainage systems. High removal is expected for mitigation system designed to remain saturated most of the time, whereas bioreactors that run periodically dry are not covered by this study. However, further experiments with the tested materials at technical or field scale under more realistic climate conditions need to be carried out.