A modelling concept is presented that enables a quantitative evaluation of transport and natural attenuation processes during bank filtration. The aim is to identify ranges of degradation rates for which bank filtration is effective or ineffective. Such modelling should accompany experimental work, as otherwise the meaning of determined degradation rates for a field situation remains uncertain. The presented concept is a combination of analytical and numerical methods, solving differential equations directly for the steady state. It is implemented using FEMLABs code and demonstrates a typical idealized situation with a single well near a straight bank boundary. The method can be applied to confined, to unconfined and to partially confined/unconfined aquifers and may be extended for applications in more complex situations, including a clogging layer, galleries of pumping and recharge wells, etc.

Reactive multicomponent transport modeling was used to investigate and quantify the factors that affect redox zonation and the fate of the pharmaceutical residue phenazone during artificial recharge of groundwater at an infiltration site in Berlin, Germany. The calibrated model and the corresponding sensitivity analysis demonstrated that temporal and spatial redox zonation at the study site was driven by seasonally changing, temperature-dependent organic matter degradation rates. Breakthrough of phenazone at monitoring wells occurred primarily during the warmer summer months, when anaerobic conditions developed. Assuming a redoxsensitive phenazone degradation behavior the model results provided an excellent agreement between simulated and measured phenazone concentrations. Therefore, the fate of phenazone was shown to be indirectly controlled by the infiltration water temperature through its effect on the aquifer’s redox conditions. Other factors such as variable residence times appeared to be of less importance.

Several physical, chemical and biological mechanisms play a role in the clogging of sediment interstices regularly observed in sand filter and infiltration basin systems. Whereas the hyporheic zone has been the focus of many investigations, little is known about the lenitic limnic zone, which is typical in lowland areas with lakes and low flow rivers. One must assume that clogging is regulated by both the build-up and the input of particulate organic matter (POM). In the present study, we collected samples from the littoral zone of Lake Tegel, Berlin, Germany, to analyze relevant carbon turnover processes. High concentrations of POM were detected in the upper sediment layer, with 3.4% ds down to 20 centimeters depth. A very high biomass of interstitial algae was found in the first 5 cm of sediment (25 µg Chl a per cm–3); this was 1000 times higher than in the lake water. The pore system of the sediment was filled to about 50% with POM, and the algae volume comprised about 25 % of POM. Only low amounts of POM were transported from the lake water downwards into the interstices, and the transport of FPOM (a few centimeters per day) was much lower than the water flow (32–260 cm d–1). The DOC concentrations in lake water (~8 mg L–1) and interstitial water (~6 mg L–1) were determined by the in situ bioactivity of interstitial organisms in addition to DOC input from lake water.

The redox conditions below an artificial recharge pond in Berlin were largely dependent on seasonal temperature changes of 0-24 °C in the infiltrate. Aerobic conditions prevailed in winter, when temperatures were low, while anaerobic conditions were reached below the pond when temperatures exceeded 14 °C. In contrast to temperature changes, cyclic changes between saturated or unsaturated conditions below the pond had only a minor effect on the redox conditions. However, the intrusion of gaseous oxygen during unsaturated conditions caused a temporary reinforced increase in oxidation of particulate organic matter. The effect of variable redox conditions on the behaviour of a number of pharmaceutically active compounds, namely carbamazepine, phenazone and several phenazone-type PhACs, was investigated. Phenazone is redox sensitive and was generally fully degraded before reaching the first groundwater well, as long as oxygen was present. When conditions turned anaerobic, phenazone was not fully eliminated. 1-Acetyl-1-methyl-2-dimethyl-oxymoyl-2-phenylhydrazide (AMDOPH) and carbamazepine are very persistent drug residues. However, results suggest that AMDOPH may be slightly degradable under aerobic conditions too, but further studies will be needed to verify this statement.

Indicator bacteria and coliphages along the transects of Lake Tegel, Lake Wannsee and the artificial recharge pond Tegel The indicator microorganisms, Escherichia coli, intestinal enterococci, and coliphages were analysed in water samples from both transects for bank filtration at the Lakes Tegel and Wannsee as well as from the artificial recharge pond of Tegel. Surface water samples of both lakes were examined from May 2002 to December 2004. In addition, samples were analysed from four shallow observation wells and three pumping sites for drinking water supply along the transect Wannsee, as well as four deep and seven shallow observation wells and 2-3 pumping sites along the transect of Lake Tegel. Sampling at the artificial recharge pond of Tegel was carried out during four field surveys (August 2002-December 2002) in two shallow, three deep wells and one pumping well for drinking water supply. In addition, the microbial flora was studied in the sand filter of the recharge pond in Tegel.

The spatial and temporal evolution of the seepage water chemistry below an artificial recharge pond was investigated to identify the impact of dynamic changes in water saturation and seasonal temperature variations. Geochemical analysis of the pond water, suction cup water and groundwater showed that during summer, nitrate and manganese reducing conditions dominate as long as saturated conditions prevail. Iron and sulphate reduction occur only locally. When the sediment below the pond becomes unsaturated, atmospheric oxygen penetrates from the pond margins leading to re-oxidation of previously formed sulphide minerals and enhanced mineralisation of sedimentary particulate organic carbon. The latter promotes the dissolution of calcite. During winter, both the saturated and the unsaturated stage were characterised by aerobic conditions. Thereby, nitrification of sedimentary bound nitrogen could now be observed because nitrate is not immediately consumed, as is the case during summer. This suggests that nitrification below the pond might be less affected by seasonal temperature changes than nitrate reduction.

To evaluate the potential hazard of a harmful substance on its pathway from a source to a sensitive site, it is important to know if degradation or reversible sorption is the dominant process. While, in case of degradation, mass is removed from the system, in the case of reversible sorption the transport is only retarded. A mathematical analytical concept is outlined, which can be applied to evaluate data from field experiments, from technical and semitechnical facilities and from the laboratory. The concept is exemplified on a series of enclosure experiments performed with phages within a project investigating processes during bank filtration. Results show that parameters are not constant in the experiments and indicate a significant influence of redox conditions on both retardation and deactivation rates. On the other hand, an influence of the clogging layer could not be detected.