This study exemplifies the use of Life Cycle Assessment (LCA) as a tool to quantify the environmental impacts of processes for wastewater treatment. In a case study, the sludge treatment line of a large wastewater treatment plant (WWTP) is analysed in terms of cumulative energy demand and the emission of greenhouse gases (carbon footprint). Sludge treatment consists of anaerobic digestion, dewatering, drying, and disposal of stabilized sludge in mono- or co-incineration in power plants or cement kilns. All relevant forms of energy demand (electricity, heat, chemicals, fossil fuels, transport) and greenhouse gas emissions (fossil CO2,CH4,N2O) are accounted in the assessment, including the treatment of return liquor from dewatering in the WWTP. Results show that the existing process is positive in energy balance (–162 MJ/PECOD * a) and carbon footprint (–11.6 kg CO2-eq/PECOD *a) by supplying secondary products such as electricity from biogas production or mono-incineration and substituting fossil fuels in co-incineration. However, disposal routes for stabilized sludge differ considerably in their energy and greenhouse gas profiles. In total, LCA proves to be a suitable tool to support future investment decisions with information of environmental relevance on the impact of wastewater treatment, but also urban water systems in general.

A pilot plant with a full scale monolithic ceramic membrane was operated at Ruhleben wastewater treatment plant (WWTP), Berlin Germany, for more than 12 months. Filtration performance according to the applied pre-treatment (dose of ozone and coagulant) were investigated. Trial runs with and without ozone, varying the operational parameters such as flux, coagulant dosage, and filtration time were conducted in order to identify the benefits of pre-ozonation. The reduction of the total fouling rate by ~70 % when applying a specific ozone dose between 1.0 and 1.4 mg mgDOC–1 highlights the potential of ozonation as pre-treatment step. Using LC-OCD measurements, the effect of ozone on the biopolymer concentration and the DOC fraction was demonstrated.

The study aims at assessing in long-term trials a gravity-driven ultrafiltration pilot plant designed for a capacity of 5 m3/d. The unit was operated in South Africa with Ogunjini surface water and was run with restricted chemical intervention or maintenance (no backflush, no aeration, no crossflow and no chemical). Under South African environmental conditions and with direct filtration of the river water and only one manual drainage of the membrane reactor every weekday, the unit could fulfil the design specification in terms of water production (5 m3/d) as long as the turbidity of the raw water remained in a reasonable level (up to 160 NTU), with a filtration flux typically 4 to 6 L/h.m² (corrected at 20°C). This value was in the same range as the lab results and was consistent with the first phase results (around 5-7 L/h.m² after biosand filtration). However, the flux dropped significantly to a range of 2 to 4 L/h.m² after a rain event resulting in a turbidity peak over several days up to > 600 NTU. This demonstrated that for variable raw water types with expected turbidity peaks above 100 NTU, a pre-treatment would be required for the system (biosand filter or other). The performance of microbiological tests confirmed the integrity of the membrane and the ability of the system to achieve advanced disinfection.

Niederdruckmembranen (Mikro- und Ultrafiltrationsmembranen) stellen eine leistungsfähige Technik zur weitergehenden Behandlung kommunaler Abwässer dar. Neben den Vorteilen eines kleinen Flächenbedarfs und eines verlässlichen Betriebes, birgt vor allem die hohe Ablaufqualität das Potential, die aufnehmenden Gewässer zu entlasten. Ein großes Problem beim Einsatz solcher Membranen ist das Membranfouling. Dieses führt zur raschen Abnahme der Filtrationsleistung, zur Erhöhung der Reinigungsfrequenz und des Chemikalieneinsatzes, was insgesamt hohe Betriebskosten verursacht. Sowohl gelöste organische Stoffe, als auch kolloidale und partikuläre Wasserinhaltsstoffe wurden als Hauptverursacher des Foulings von Niederdruckmembranen identifiziert. Durch gezielte Vorbehandlungen des Wassers kann das Membranfouling deutlich reduziert werden. Verschiedene Studien zeigen, dass eine vorgeschaltete Flockung zur Ausbildung eines porösen, hydraulisch gut rückspülbaren Filterkuchens führt. Weiterhin konnte gezeigt werden, dass eine Kombination aus Ozonung und Flockung durch den Effekt der Mikroflockung eine Bildung größerer, stabilerer Flocken bewirkt und somit eine verbesserte Filtrierbarkeit des Wassers erreicht werden kann. Bisher fehlt jedoch die Möglichkeit, verlässliche Vorhersagen über das Foulingpotential von gereinigtem Abwasser zu treffen. Das Ziel dieser Studie ist es, auf Grundlage von Partikelgrößenanalysen im nm-Bereich, Abschätzungen über das Foulingverhalten von Kläranlagenablauf zu treffen. Darauf aufbauend soll die Vorbehandlung aus Ozonung und anschließender Flockung für die Minimierung des Foulingpotenzials der im Wasser enthaltenen Substanzen optimiert werden.

Previously, the analysis of energy demand for wastewater treatment was often limited to one-dimensional analyses of electricity demand. How ever, a comprehensive analysis requires the inclusion of all different contributions to energy demand. The Life Cycle Assessment (LCA) methodology defined in ISO 14040/44 is a suitable tool for this task. With it, all different primary and secondary energy demands can be quantified and assessed using consistent indicators, complemented by an assessment of other environmental impacts such as the carbon footprint.

This paper presents the results of an evaluation of the environmental footprint of the Braunschweig wastewater scheme with Life Cycle Assessment. All relevant inputs and outputs of the system are quantified in a substance flow model and evaluated with a set of environmental indicators for cumulative energy demand, carbon footprint, acidification, eutrophication, and human and ecotoxicity. The analysis shows that energy demand and carbon footprint of the Braunschweig system are to a large extent offset by credits accounted for valuable products such as electricity from biogas production, nutrients and irrigation water. The eutrophication of surface waters via nutrient emissions is reduced in comparison to a conventional system discharging all effluent directly into the river, because some nutrients are diverted to agriculture. For human and ecotoxicity, a close monitoring of pollutant concentrations in soil is recommended to prevent negative effects on human health and ecosystems. Normalised indicators indicate the importance of the primary function of the wastewater system (= protection of surface waters) before optimisation of secondary environmental impacts such as energy demand and carbon footprint. A further decrease of the energy-related environmental footprint can be reached by applying optimisation measures such as the addition of grass as co-substrate into the digestor, thermal hydrolysis of excess sludge, or nutrient recovery from sludge liquors.