Different technologies for tertiary wastewater treatment are compared in their environmental impacts with Life Cycle Assessment (LCA). Targeting low phosphorus concentration (50-120 µg/L) and disinfection of WWTP secondary effluent, this LCA compares high-rate sedimentation, microsieve, dual media filtration (all with UV disinfection), and polymer ultrafiltration or ceramic microfiltration membranes for upgrading the large-scale wastewater treatment plant Berlin-Ruhleben. Results show that mean effluent quality of membranes is highest, but at the cost of high electricity and chemicals demand and associated emissions of greenhouse gases (GHG) or other air pollutants. In contrast, gravity-driven treatment processes require less electricity and chemicals, but can reach significant removal of phosphorus. In fact, the latter options will only lead to a minor increase of GHG emissions and energy demand compared to the existing pumping station or UV treatment.

Im BMBF-Forschungsverbund „Risikomanagement von neuen Schadstoffen und Krankheitserregern im Wasserkreislauf (RiSKWa)“ wurde die Definition von „Indikatorsubstanzen“ als ein interessantes Querschnittsthema identifiziert. Es wurde dazu eine Arbeitsgruppe gebildet, die sich die Aufgabe stellte, einen Leitfaden zur Zweckbestimmung, Auswahl, Bedeutung und Interpretation von polaren organischen spurenstoffen als chemische Indikatoren zu verfassen. Mit Hilfe der Indikatoren sollten insbesondere anthropogene Veränderungen der Wasserqualität erkennbar sein, sowie natürliche Prozesse und technische Aufbereitungsverfahren überwacht und gesteuert werden können. Diese Indikatoren dienen nicht der Bewertung der Wasserqualität. Mögliche Anwender sind die Bearbeiter in den Verbundvorhaben des RiSKWa-Programms und in weiteren Vorhaben in den Bundesländern, die sich mit Spurenstoffen befassen, Fachbehörden, Forschungseinrichtungen, Wasserlabors der Trinkwasserversorgung und Abwasserreinigung und Ingenieurfirmen, die wassertechnologische Themen der Spurenstoffentfernung bearbeiten. Einen Überblick über mögliche Quellen, Eintragspfade und Barrieren im Wasserbereich zeigt die folgende Abbildung aus dem Bericht eines DECHEMA-Arbeitsausschusses „Pfad- und wirkungsspezifische Indikatorsysteme für Wasser- und Bodensysteme“ (Leitung: W. Dott). Dieser Leitfaden wird dabei sehr wesentliche Teile des dargestellten Systems behandeln.

Approximately 70% of the drinking water in Germany (BGR) and about 50% worldwide (IGREC 2011) are abstracted 2 from groundwater using filter wells. Their implementation and operation are major factors contributing to the costs of drinking water production. Within the joint research project ANTIOCKER , funded by the German Ministry of Research and Education, and coordinated at the Dept. of Applied Microbiology of the Technical University Berlin, the partners Berliner Wasserbetriebe (BWB) and the Berlin Centre of Competence for Water (KWB) focus on the efficient operation of drinking water abstraction wells. One major reason for inefficient wells is so-called well ageing, i.e. the increase in drawdown at constant discharge rate due to biological, chemical and / or physical processes in and around the well. In Berlin, approximately 80% of clogging deposits are described to be of biochemical nature involving iron-related bacteria. Previous studies, i.e. in the scope of the KWB research project WELLMA have revealed that such well ageing phenomena are determined by multiple correlated biological and chemical processes. For this reason, it is the sound understanding of the main processes and key parameters that will provide the basis for the systematic control of iron bacteria occurrence by an optimized well operation. A new approach to a large variety of data from well construction and maintenance of the Berlin drinking water wells focused on the determination of key parameters for monitoring and the identification of hidden variables for ageing by means of probabilistic statistics. Cumulative distribution plots are used to visualize large data amounts and frequency distribution plots filter correlations between e.g. maintenance events in the lifetime of a well and monitoring data. First results indicate that small changes in the discharge rate Q on a daily basis could be used to monitor the well performance on a much higher frequency than the currently used evaluation of the specific capacity. In addition, the electric conductivity proved to be a key variable for clogging. Both parameters are now being verified in field investigations and further data analyses within the research project ANTIOCKER and about 50% worldwide are abstracted 2 from groundwater using filter wells. Their implementation and operation are major factors contributing to the costs of drinking water production.

The effect of combined sewer overflow (CSO) control measures should be validated during operation based on monitoring of CSO activity and subsequent comparison with (legal) requirements. However, most CSO monitoring programs have been started only recently and therefore no long-term data is available for reliable efficiency control. A method is proposed that focuses on rainfall data for evaluating the effectiveness of CSO control measures. It is applicable if a sufficient time-series of rainfall data and a limited set of data on CSO discharges are available. The method is demonstrated for four catchments of the Berlin combined sewer system. The analysis of the 2000–2007 data shows the effect of CSO control measures, such as activation of in-pipe storage capacities within the Berlin system. The catchment, where measures are fully implemented shows less than 40% of the CSO activity of those catchments, where measures have not yet or not yet completely been realised.

The impact of a pre-treatment by pre-ozonation (2-10 mg O3/L) and subsequent coagulation (FeCl3: 2-6 mg Fe3+/L) on the performance of a polymeric ultrafiltration membrane was studied. No free dissolved ozone was in contact with the membrane. Lab tests were performed using Amicon test cells fed with secondary effluent and the flux decline during filtration tests was measured. Flux decline was reduced with increasing coagulant concentration as well as with increasing ozone dosage. This effect was confirmed by a reduction in the amount of biopolymers measured with size exclusion chromatography by organic carbon detection (LC-OCD). Conducted multi filtration cycles revealed a significant increase in irreversible fouling after pre-ozonation that might be caused by increasing colloidal iron concentrations. Phosphorus in the permeate was successfully reduced to concentrations < 60 µg/L

The Berliner Wasserbetriebe are the largest water supply and wastewater disposal company in Germany. They are challenged to tackle various kinds of odour problems emerging from the sewer network. The continuous extension of sewer networks and a decrease in water consumption (in Berlin: ~ 20 % in the last 16 years, according to the statistical office BB, 2009) have led to elevated odour emissions arising from sewer systems. Together with growing public concern over odours from water treatment works, this has led to increasing numbers of odour complaints in urban catchments (Stuetz and Frechen, 2001; ATV-DVWK-M 154, 2003; Barjenbruch, 2003). Different odour abatement technologies are widely-used but often response only after consumer complaints and do not consider adequate identification of odour problems beforehand. An operational, together with a scientific approach is necessary in order to apply effective measures or combinations thereof. In Berlin annually almost 3 Mio € are spent by BWB to reduce odour emissions from the Berlin sewer system (BWB, 2006). Applied measures vary from dosing of nitrate or iron hydroxide sludge, flushing, or compensation by means of bio-filters or masking. The quantification of odour by means of continuous odour monitoring solutions such as electronic noses can contribute to minder economic and operational risks in odour management. The paper presents the research project ODOCO-ARTNOSE, dealing with the evaluation of electronic noses for the online application in sewer systems. The KompetenzZentrum Wasser Berlin (research centre) in cooperation with the Berlin water utilities Berliner Wasserbetriebe and Veolia Water will carry out bench tests with selected, commercially available chemosensor arrays to identify advanced applications of electronic noses in odour management in sewer networks. Objectives of the project are to analytically assess the online-ability of electronic noses by means of a multi-criteria methodology and to specify future odour control services based on the application of e-noses in sewer networks. The potential of electronic noses will be evaluated as tool to fulfil certain needs, namely (i) support for planning/designing of odour preventive measures and abatement strategies, (ii) support for real-time odour control and (iii) data acquisition tool to supervise and document (industrial) dischargers, document the effect of abatement measures and document legal compliance. Tests are possible to be carried out in the frame of a sewer research plant or within the sewer system of Berlin. A large-scale research plant was developed by Berliner Wasserbetriebe for investigating different odour and corrosion strategies. The plant consists of 2 independent gravity lines and is fed by combined wastewater from Berlin, pumped directly from the sewer. Various milieu conditions can be generated. The paper places current challenges within the city of Berlin into perspective and displays examples of odour abatement strategies of Berliner Wasserbetriebe. Expected outcomes and correlated benefits of the project will be presented. The methodological approach relies on a transparent selection of chemosensor array systems, on bench tests following a sophisticated measurement program and the evaluation of the electronic noses by clear defined criteria.